Do you know how physicochemically sunscreen neutralizes UV rays?

in #science7 years ago (edited)

Hello Steemit! This time I want to talk about sunscreens, which are so necessary for skin care today. Perhaps, we have used them in oil, creams or gel, but do you really know which compounds they have and how they work? Well, in this post I will explain how the action of the sun rays on the skin is stopped, by means of this product. I hope you enjoy it.

Ultraviolet radiation

On these days of summer, it is common to use sunscreens. It is the first thing that people, take to the beach to protect themselves from the inclemencies of the sun and thus avoid burns that in time can become something more serious.

protectorSolar 1.jpg

Sunscreens

The first thing we need to know is that the sun emits radiations that reach the Earth with the highest energy being ultraviolet (UV) radiation, which can be divided from high to low energy into UV-A, UV-B and UV- C. However, as the Earth's atmosphere absorbs much of this radiation, most of the ultraviolet rays that reach the surface of our planet are of the UV-A type, these rays are responsible for the shrinkage, which is usually not very long-lasting. They have the ability to penetrate to the deepest layers of the dermis, where they generate free radicals that can deteriorate the elastin and collagen of the skin, causing premature aging together with the appearance of wrinkles, stains and lack of elasticity, as well as causing Cancer. In the case of UV-B they reach 1%, penetrate less than UV-A, but they are more reflective, can cause damage to the body by burning tissue and increase the risk of cancer, making them the most dangerous. Finally, UV-C radiation does not reach the earth because it is completely absorbed by the oxygen and ozone in the atmosphere, so there is no danger.

Sunscreens: Physicists and Chemists

All these factors have been taken into account for years by scientists for the manufacture of sunscreens, which use specific compounds that have the ability to filter these rays harmful to our health. How do sunscreens have to be? Well, they are divided into two types, Physicists and Chemists.

Physical sunscreens which are usually composed of titanium and zinc oxides are fluorescent and their particles are deposited on the skin reflecting the radiation. Fluorescence is a phenomenon whereby ultraviolet radiation is absorbed and emitted as radiation of lower energy, in this case the emitted radiation falls within the visible spectrum, reason why these protectors diminish the danger of the radiation. Because of this, generally the protective creams or gels are an intense white color. With these creams, in addition to avoiding erythema, it prevents tanning. The sunscreens that use this type of filter usually indicate in their packaging "total screen effect".

fluoresencia 2.png
Fluorescence (1) absorption (3) emission

Chemical sunscreens in turn, are composed of substances that are activated by photochemical reactions absorbing ultraviolet radiation by capturing the energy of the sun's rays, and transforming it into thermal energy not harmful to the skin. Mainly, the chemical filters are based on aromatic derivatives that have the pi-conjugate bonding system.

In nature we can find chemical filters such as β-carotene that can be found in carrots. β-carotene is a precursor of vitamin “A” and its antioxidant properties can neutralize the action of free radicals produced by ultraviolet rays. This molecule possesses alternate double bonds in which the electrons can jump between the different pi orbitals absorbing slightly the ultraviolet rays.

beta carotene.jpg

β-carotene

Finally, protecting ourselves from the sun's rays is a serious matter, the application of protectors can prevent damage to the skin caused by UV rays. Knowing what sunscreens are made of and how they work can give us an idea of the magnitude of the issue.

If you liked the post and want to continue seeing more articles of this type, upvote, follow me and resteem.

References

Hughes, M. C. B., Williams, G. M., Baker, P., & Green, A. C. (2013). Sunscreen and Prevention of Skin AgingA Randomized Trial. Annals of internal medicine, 158(11), 781-790.

Iannacone, M. R., Hughes, M. C. B., & Green, A. C. (2014). Effects of sunscreen on skin cancer and photoaging. Photodermatology, photoimmunology & photomedicine, 30(2-3), 55-61.

Wondrak, G. T. (2014). Sunscreen-based skin protection against solar insult: molecular mechanisms and opportunities. In Fundamentals of Cancer Prevention (pp. 301-320). Springer Berlin Heidelberg.

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I have found many sunscreens simply don't work, and I don't like the chemicals in them. A natural one - Manda paste - is great - healthy enough to eat!
And it was developed by surfers so it doesn't come off while in the water!

Did you know outdoor workers have a very low instance of carcinoma? Some believe it is because they get the early morning sun - mostly red and near infrared light. This provides some protection from the harmful UV aspects.

But we shouldn't eliminate UV light from our lives! Even with vitamin D in a pill, we still need the natural UV rays to activate the making of vitamin D.

Some of the chemicals in sunscreens can be degraded by light and eventually absorbed through the skin, so there may be a risk of intolerance. This should be taken into account in the choice of these filters.

I find it very interesting what happens to the workers in the open air. Certainly UV rays play an important role in our lives, we should only avoid excesses.

Its nice that you comment on this post. I hope to see you soon in others. I follow you.

Wow!! It's really interesting to understand how this all works!! You got my upvote and nice post!!

thanks, It's nice that you like it.

Nice article! Nice to meet another chemist here !!!
It is true that β-carotene is a good radical scavenger. For most of the time, chemical sun screen protect your skin by absorbing UV energy for pericyclic reactions or excitation to give carbonyl oxide diradical and dissipate the UV energy

Nice comment, is nice to meet a another chemist too. β-carotene is one of the millions of examples of how wonderful is the chemistry in nature. I hope to see you soon in the next post. I follow you.

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