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RE: THE ONLY GOOD SNAKE IS A DEAD SNAKE?!?!? : How to Handle a Wild Snake Encounter – Evaluating Your 3 Options
Pit Vipers like Rattlesnakes, Cottonmouths, and Copperheads have cat-like pupils. However, the Coral Snake is both venomous and has round pupils.
Nonvenomous snakes will all have round pupils as far as I know.
You can see the "cat eyes" in the three pit vipers I photographed for this post.