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RE: Which cup will fill up First ?
If the fluid has a viscosity simmilar to that of watet it would over flow the third recepticle and the overflow may travel along the outside of the tube leading to the 5th and 4th recepticle. This all depends on what the fluids viscosity is and the rate at which it is being released from the spicket.
Viscosity is relevant to flow. Even if it is water, if the flow is fast enough, it won't matter.